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Sign into your 23andMe account at https://you.23andme.com
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At the top of the page, click “Tools”
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At the bottom of the “Tools” page, click “Raw Data”
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On the “Raw Data” page, Click the “Download” link.
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Select “All DNA”, enter your password and click the “Download Raw Data” button.
For more detailed description:
http://www.dnaadoption.com/uploads/DNAadoption/DNAadoption_files/To_Download_Raw_Data.pdf